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EXTRACTION OF Zn AND Cd FROM CHLORIDE LIQUORS BY TRI-n-BUTYL PHOSPHATE

JIANG Tao SU Yuanfu Chemical Engineering Research Center , East China University of Chemical Technology , Shanghai , China

金属学报(英文版)

Studies have been made on the extraction of Zn and Cd by TBP(tri-n-butyl phosphate) from diluent hydrochloric acid solutions of soldium chloride.The experiments show that the species extracted from diluent HCI solutions of NaCl appear to be predominantly ZnCl_2· 2TBP and CdCl_2·2TBP.For Cd,at lower acidities,anionic complexes of the type H_2CdCl_3 are also extracted.As the acidity is increased,H_2CdCl_4 appear to be predominant complexes in organic phase.For Zn,the acidocomplexes of the type HZnCl_3 appear in organ- ic phase after the acidity of solutions reaching a certain value([HCl]>0.1 mol/L). Furthermore,the ultraviolet absorption spectra of both aqueous and organic phases have been studied,and the infrared spectra of the organic phases have been exomined.The extraction mechanism and temperature effect are also discussed.

关键词: extraction , null , null , null , null , null

CORRELATION BETWEEN STRESS COMPONENTS AND STRESS CORROSION CRACKS IN BRASS Lecturer,Department of Materials Physics,University of Science and Technology Beijing,Beijing 100083,China

QIAO Lijie LIU Rui XIAO Jimei University of Science and Technology Beijing , Beijing , China

金属学报(英文版)

The effects of stress components on nucleation sites and propagation directions of stress cor- rosion cracks in brass were investigated with specimens under mode Ⅱ and mode Ⅲ loadings. The results indicated that under mode Ⅱ loading,stress corrosion cracks nucleated on the site with maximum normal stress component and propagated along the plane perpendieular to the maximum normal stress,under mode Ⅲ loading,the stress corrosion crack was not evident on the 45°plane due to the general corrosion in aqueous solution with high NH_4OH concentra- tion,while stress corroded in aqueous solution with low NH_4OH concentration, numerous cracks with spacings of 10—150μm were found on the 45°plane with maximum normal stress and no stress corrosion cracks was observed on the plane with maximum shear stress.

关键词: stress corrosion cracking , null , null , null

Developing carbon materials targeted for applications-A summary on the annual world conference on carbon, Carbon2011

新型炭材料

The 2011 Annual World Conference on Carbon (Carbon 2011) was held in Shanghai, China, during 24-29 July, 2011. This conference was hosted jointly by East China University of Science and Technology, University of Shanghai for Science and Technology, and Institute of Coal Chemistry Chinese Academy of Sciences. About 800 attendees from 42 countries/regions participated in this conference, and 797 papers were accepted for presentation, including 5 plenary lectures, 42 keynote lectures, 280 oral presentations, and 470 posters, involving 10 topics: graphene; nanocarbon, carbon for energy storage and conversion, porous carbon and adsorption, carbon fiber and composites, precursor/carbonization and graphitization, computation and modeling, bio-carbon and safety, novel experimental techniques and characterization, bulk carbon and industrial applications. Research and development of nanocarbons are quite active and in particular, graphene received tremendous interest. Rapid progress has also been made on the electrochemical properties, energy conversion and energy storage applications of carbon materials.

关键词:

EAST装置罗柯线圈测试与电磁干扰分析

郑龙贵 , 陆建华 , 吕环宇 , 潘超 , 肖业政 , 倪其才 , 朱崇铭

低温物理学报

本文主要介绍了EAST实验中罗柯受电磁干扰的影响,由实验现象推测产生噪声的原因,通过大量的探索过程和模拟测试方法最终将这些干扰有效的抑制和去除,得到最佳解决方案.

关键词: 罗柯 , 电磁干扰 , 测试方法 , 干扰抑制

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